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A diprotic acid is titrated with NaOH solution of known concentration. Molecular weight (or molar mass) is found in g/mole of the diprotic acid. Weighing the original sample of acid will tell you its mass in grams. Moles can be determined from the volume of NaOH titrant needed to reach the first equivalence point.
For diprotic acids, titration curves allow you to calculate the Ka1 and Ka2 of the acid. therefore, the pH at the half-‐first equivalence point in a titration equals the pKa1 of the acid. therefore, the pH at the half-‐second equivalence point in a titration equals the pKa2 of the acid.
025 gram, but you want to find the molar mass, or the mass for one mole. So, set up another proportion: x/. 025 g = 1 mol/. 00315 mol, and you find that x = 7.94 grams, which is the molar mass of the acid.
You used twice the amount of water to dissolve the acid. Adding twice the amount of water to the acid would not alter the molar mass because the volume of DI water added to the acid was not recorded and was not part of the calculations to find the molar mass.
Diprotic acids, such as sulfuric acid (H2SO4), carbonic acid (H2CO3), hydrogen sulfide (H2S), chromic acid (H2CrO4), and oxalic acid (H2C2O4) have two acidic hydrogen atoms. Triprotic acids, such as phosphoric acid (H3PO4) and citric acid (C6H8O7), have three.
A diprotic acid is titrated with NaOH solution of known concentration. Molecular weight (or molar mass) is found in g/mole of the diprotic acid. Weighing the original sample of acid will tell you its mass in grams. Moles can be determined from the volume of NaOH titrant needed to reach the first equivalence point.
The total number of diprotic acids among the following is: H3PO4,H2SO4,H3PO3,H2CO3, H2S2O7,H3BO3,H3PO2,H2CrO4,H2SO3.
Sulfurous acid ( H2SO3 ) is a diprotic acid with Ka1=1.39×10−2 and Ka2=6.73×10−8.
Carbonic acid, H2CO3, is a diprotic acid for which K1 = 10^-7 and K2 = 10^-11.
Use the titration formula. If the titrant and analyte have a 1:1 mole ratio, the formula is molarity (M) of the acid x volume (V) of the acid = molarity (M) of the base x volume (V) of the base. Multiply the molarity of the acid by the volume of the acid (1.25 x 35).
Concentration formula: To find the molar concentration of a solution, simply divide the total moles of solute by the total volume of the solution in liters.
The equivalence point is defined as the point where the moles of strong acid added = initial moles of base B in solution. Graphically, the equivalence point is where the curve is most vertical.
Polyprotic acid are able to donate more than one proton per acid molecule, in contrast to monoprotic acids that only donate one proton per molecule. A diprotic acid dissociationThe diprotic acid has two associated values of Ka, one for each proton. Likewise, a triprotic system can be envisioned.
Therefore, a monoprotic acid is an acid that can donate only one proton, while polyprotic acid can donate more than one proton. Similarly, a monoprotic base can only accept one proton, while a polyprotic base can accept more than one proton.